{ "@context": "http://iiif.io/api/presentation/3/context.json", "id": "https://opennj.net/iiif/manifest/AA00001405/00001", "type": "Manifest", "label": { "none": [ "General Chemistry Supplement" ] }, "metadata": [ { "label": { "en": [ "Abstract" ] }, "value": { ",": [ "This general chemistry \u0022text\u0022 was written by Emily V Eames as a supplement to a standard textbook. It includes both \u0022overview\u0022 sections, providing summaries of most important info, and \u0022story\u0022 sections, providing richer knowledge of history and applications.-LibreTexts" ], "none": [ "Chemistry Basics-\nAlchemy\nAncient History\nAtomic Structure\nAtomic Theory\nDiscovering Sub-atomic Particles\nElectricity and Electrochemistry\nGay-Lussac\u0027s Law\nIntroduction\nLavoisier\nMeet the Periodic Table\nNomenclature\nScientific Method\nValence and the Periodic Table\n\nChemistry Calculations-\nChemical Equations\nDimensional Analysis\nDimensional analysis means thinking about units piece by piece. Dimensional analysis can by to correctly go between different types of units, to catch mistakes in one\u0027s calculations, and to make many useful calculations in real life. Essentially, dimensional analysis means multiplying by one. You collect a set of \u0022conversion factors\u0022 or ratios that equal one, and then multiply a quantity that you are interested in by those \u0022ones.\u0022\nMolarity\nMoles\nSignificant Figures\nSignificant figures, often called sig figs, are the number of digits in a given value, or number. For instance, 18 has 2 sig figs, and 3.456 has 4 sig figs. However, both 10 and 1000 have only 1 sig fig. The reason is because the zeros have to be there to show what the number is, so they don\u0027t count as significant digits.\nStoichiometry\nTitrations\nA titration is a laboratory technique used to precisely measure molar concentration of an unknown solution using a known solution. The basic process involves adding a standard solution of one reagent to a known amount of the unknown solution of a different reagent.\n\nChemical Reactions and Interactions-\nAcid-Base Reactions\nCombination Reactions\nCombination reactions describe a reaction in which two or more reactants become one product (are combined). The problem with this term is that it doesn\u0027t give you much chemical insight because there are many different types of reactions that follow this pattern. So we\u0027ll break it into groups that reflect what\u0027s actually happening a little better.\nCombustion Reactions\nDecomposition Reactions\nElectrolyte Strength\nElectrolyte means a solute that allows a water solution to conduct electricity. Electrolytes produce ions when they dissolve in solution. Salts are usually electrolytes, while molecular substances usually aren\u0027t, unless they are acids or bases.\nOverview\nRedox Reactions\nSolubility and Precipitation\nSolutions, Solvation, and Dissociation\nDissolution means the process of dissolving or forming a solution. When dissolution happens, the solute separates into ions or molecules, and each ion or molecule is surrounded by molecules of solvent. The interactions between the solute particles and the solvent molecules is called solvation.\nThe Wild Ionists\nFaraday proved that pure water doesn\u0027t conduct electricity, but conductivity increases when some types of solutes are added. These solutes are called electrolytes. For a long time, people thought that the ions that let water conduct electricity (to conduct, charged particles must move, such as electrons through a metal wire or ions through solution) were formed by the electricity.\n\nGases-\nDiffusion and Effusion\nGas Laws\nIntro to Gases\nKinetic-Molecular Theory\nPartial Pressures\nPressure\nReal Gases\n\nLewis Bonding Theory-\nDrawing Lewis Structures\nLewis Acid-Base Theory\nLewis and Lagmuir\nMagnetism\nPolarity of Chemical Bonds\nThe Octet and Other Stable Groups\nThe Two-Electron Bond\n\nValence Bond Theory-\n3-D Structures of Molecules\nDipole Moments\nElectronegativity\nFormal Charges in Lewis Structures\nHybrid Orbitals\nMultiple Bonds\nOverview of Pauling and Valence Bond Theory\nResonance\nStrengths of Covalent Bonds\n\nMolecular Orbital Theory-\nFrontier MOs: An Acid-Base Theory\nIntro to MO Theory\nMixing Orbitals to Make MOs\nMO Diagrams for First Row Diatomic Molecules\nMO Diagrams for Heterodiatomic Molecules\nMO Diagrams for Linear Triatomic Molecules\nConstruct MO diagrams for simple linear triatomic molecules and/or compounds\nMO Diagrams for Water and Nitrate Ion\nMO Theory: Simplest Examples\nReading and Writing MO Diagrams\nTypes of MOs\n\nPeriodic Trends-\nCharacteristics of Metals\nCharacteristics of Nonmetals\nEffective Nuclear Charge\nElectron Affinity\nIonization Energy\nIonization energy is the energy needed to remove an electron from an atom or ion. Unlike atomic radii, we can and do measure ionization energies in the gas phase, when the atom or ion is not interacting with anything else.\nSizes of Atoms and Ions\nSlater\u0027s Rules for Effective Nuclear Charge\nEffective nuclear charge determines the size and energy of orbitals, which determine most properties of atoms. Slater\u0027s rules give a simple approximation of effective nuclear charge, which depends on the number of electrons that might get between, so it depends on the electron we are looking at. For any electron, to find the effective nuclear charge it feels, we need to know how many other electrons might get in the way, and how much time it spends near the nucleus.\n\nPhases and Intermolecular Forces-\nDipole-dipole Forces\nHydrogen Bonding\nIntro to Phases and Intermolecular Forces\nLiquids\nLondon Dispersion Forces\nPhase Changes\nPhase Diagrams\nVapor Pressure\n\nSolids-\nCovalent-Network Solids: Semiconductors and Insulators\nCrystalline Solid Structures\nIntro to Solids\nIonic Solids\nMetallic Bonding\nMetal Crystal Structures\nOther Solids: Polymers, Nanomaterials, Foams, etc.\n\nQuantum Chemistry-\nAtomic Orbitals\nDescribing Waves\nDiscovery of Quantization\nElectron Configurations\nElectron Configurations According to Bohr and Pauli\nLight as a Wave\nParticle in a Box\nThe New Quantum Mechanics\n\nThermochemistry-\nBasic Definitions\nCalorimetry and Reaction Enthalpy\nFuels and Enthalpy\nHess\u0027 Law and Enthalpy of Formation\nHistory of Thermodynamics\nKinetic and Potential Energy\nThe First Law of Thermodynamics\nThe Zeroth Law of Thermodynamics\nWork and Heat\n-General Chemistry Supplement (Eames)" ] } }, { "label": { "en": [ "Publication Date" ] }, "value": { "none": [ "September 17, 2020" ] } }, { "label": { "en": [ "Holding Location" ] }, "value": { "none": [ "LibreTexts" ] } }, { "label": { "en": [ "External Link" ] }, "value": { "none": [ "https://chem.libretexts.org/Bookshelves/General_Chemistry/Book%3A_General_Chemistry_Supplement_(Eames)" ] } }, { "label": { "en": [ "Permanent Link" ] }, "value": { "none": [ "http://open-nj.sobeklibrary.com/AA00001405/00001" ] } }, { "label": { "en": [ "Creator" ] }, "value": { "none": [ "Eames, Emily V. " ] } }, { "label": { "en": [ "Note" ] }, "value": { "none": [ "Eames, E.V. (2020, September 17). General Chemistry Supplement. https://chem.libretexts.org/@go/page/52742" ] } }, { "label": { "en": [ "Other Item" ] }, "value": { "none": [ "https://chem.libretexts.org/Bookshelves/General_Chemistry/Book%3A_General_Chemistry_Supplement_(Eames)" ] } }, { "label": { "en": [ "Publisher" ] }, "value": { "none": [ "LibreTexts" ] } }, { "label": { "en": [ "Type" ] }, "value": { "none": [ "Book" ] } }, { "label": { "en": [ "Rights Management" ] }, "value": { "none": [ " This item is licensed with the Creative Commons Attribution License. This license lets others distribute, remix, tweak, and build upon this work, even commercially, as long as they credit the author for the original creation." ] } }, { "label": { "en": [ "Source Institution" ] }, "value": { "none": [ "City College of San Francisco" ] } }, { "label": { "en": [ "Subjects / Keywords" ] }, "value": { "none": [ "Open and Affordable Textbooks (OAT)", "Chemistry" ] } }, { "label": { "en": [ "Title" ] }, "value": { "none": [ "General Chemistry Supplement" ] } }, { "label": { "en": [ "Format" ] }, "value": { "none": [ "Book" ] } }, { "label": { "en": [ "Digital Resource Creation Date" ] }, "value": { "none": [ "11/10/2020" ] } } ], "service": [ { "@context": "http://iiif.io/api/search/2/context.json", "id": "https://opennj.net/iiif/manifest/AA00001405/00001/search", "type": "SearchService2", "profile": "http://iiif.io/api/search/2/search" } ], "seeAlso": [ { "id": "https://opennj.net/content/AA/00/00/14/05/00001/AA00001405_00001.mets.xml", "type": "Dataset", 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